Not sure how "nice" it has to be.. but some copy shops (esp. larger ones serving larger markets) have a kind of one-off perfect binding (that's the kind where the pages are glued to the cover along the spine, like a paperback book). It's a definite step above the wire/plastic binding. If they don't do it in house, they may have a place to send it out. Ask to see a sample to make sure you'd be happy with the results, though.
OR you could try Japanese bookbinding!
Sewn styles
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