Mark1
Full time employment: Posting here.
I love a good materials question;
Duplex stainless steels[1][2][3][4][5] are a family of stainless steels. These are called duplex (or austenitic-ferritic) grades because their metallurgical structure consists of two phases, austenite (face-centered cubic lattice) and ferrite (body centered cubic lattice) in roughly equal proportions. They are designed to provide better corrosion resistance, particularly chloride stress corrosion and chloride pitting corrosion, and higher strength than standard austenitic stainless steels such as Type 304 or 316.
A 2205 SS is one type, or even a lower grade 2102 duplex is best for combustion gas corrosion. These type of alloy stainless is found in quality HX for furnace application. If you ask the installing tech, he will likely not know the difference. This is primarily needed in the secondary HX that sees the condensing gases. The hotter primary HX can even be aluminized steel, since it does not have the same type of corrosive exposure due to temperatures that maintain H2O in vapor, but still an issue.
Nice summary Happyras, although, I'm a little surprised with the use of duplex within a furnace(?). Typically, duplex is never used at higher temperatures. In fact many engineering codes don't allow for it use above ~600 Deg F. due to embrittlement concerns. I guess the service temperatures most be below 600 Deg F, and the far superior resistance to Cl-SCC must be driving the material selection.
An example on SS materials;
Weber makes Gas Grills and uses 316 SS, mine lasted 15 years until it was damaged by something falling on it. It did not rust out. Chinese grills (you know the cheaper ones) are made from low cost low alloy stainless, at best 304 ss, mostly worse. They rust out in about 3 to 5 years with use. Gas has corrosive biproducts. YGWYPF.....
In terms of stainless steels, my rule of thumb is always default to the use 316 for services where pitting and crevice corrosion are a concern at lower temperatures, due to the presence of Mo within the steel. However, at higher temperatures, I would default to the use of 304 SS over 316 SS due to its superior resistance to high temperature oxidation from the increased alloying of chromium. For my grills and fire-pits I actual prefer 304 SS, although I will admit that mine would be more susceptible to attack from bird droppings, etc., so there are always trade-offs in life.