The family member saves money but what do you get? A bunch of stress and you get to miss a lot of the fun. I hope your family member knows what they're asking but I'm guessing they do not. I've done weddings and there is a reason photographers get paid. Everyone wants the group shot after the fact but cooperation getting folks together for the shots can be a daunting task.
If I were looking to save money on wedding pics I would never ask a friend or relative to do it ... I've said "no" more than once. What I would do (If you are in a metro area) is check the Craigslist "services" section. In Denver, there are always young photographers looking to build their wedding portfolio. I am always amazed at how cheap (75 - 100 bucks) some folks are willing to photograph a wedding.
Again, if you are in a metro area check to see if a local university / community college offers a course in wedding photography. When I took a wedding photo 101 class students were scrambling to find weddings to shoot and a lot of the students were already very, very good.
You asked
When asked, I did say no, that it would be too stressful on me (I don't want to be responsible for screwing up somebody's wedding pics!). But after a few weeks of looking for an alternative, I was told that they would still rely primarily on my photos. I in turn only promised photo quality commensurate with my remuneration level ($0). The wedding is taking place in Europe and most people there just don't have the kind of expectations that US newlyweds have in terms of wedding picture quality. But I want to do my best.
It's a small wedding and I know almost all the guests so hopefully getting group shots won't be like herding cats.
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